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dc.contributor.authorHussain, Muhammad Asif-
dc.contributor.authorYang, MinHo-
dc.contributor.authorJang, Hyung-Seok-
dc.contributor.authorHwang, Sung-Yeon-
dc.contributor.authorUm, Byung-Hun-
dc.contributor.authorChoi, Bong Gill-
dc.contributor.authorKim, Jung Won-
dc.date.accessioned2024-01-20T04:01:53Z-
dc.date.available2024-01-20T04:01:53Z-
dc.date.created2021-09-05-
dc.date.issued2016-06-29-
dc.identifier.issn0888-5885-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/123943-
dc.description.abstractA highly efficient two-dimensional (2D) nanocatalyst for the aerobic oxidation of amines, consisting of ruthenium-exfoliated molybdenum disulfide (Ru@E-MoS2), was investigated. As-synthesized Ru@E-MoS2 yielded the nitriles from various aromatic, aliphatic, allylic, and heteroatomic amines with high selectivity in molecular oxygen as terminal oxidants. The Ru@E-MoS2 experienced an improved catalytic activity for benzylamine and p-substituted benzylamine derivatives and produced good turnover numbers (TONs) for aliphatic amines. Moreover, the heterogeneous Ru@E-MoS2 nanocatalyst maintained its catalytic performance for five cycles of benzylamine oxidation reaction.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectCATALYTIC-ACTIVITY-
dc.subjectEFFICIENT-
dc.subjectOXIDE-
dc.subjectDEHYDROGENATION-
dc.subjectBENZYLAMINES-
dc.subjectCOMPLEX-
dc.subjectOXYGEN-
dc.titleTwo-Dimensional Heterogeneous Ruthenium-Molybdenum Disulfide Nanocatalyst for the Selective Aerobic Oxidation of Amines-
dc.typeArticle-
dc.identifier.doi10.1021/acs.iecr.5b04162-
dc.description.journalClass1-
dc.identifier.bibliographicCitationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.55, no.25, pp.7043 - 7047-
dc.citation.titleINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH-
dc.citation.volume55-
dc.citation.number25-
dc.citation.startPage7043-
dc.citation.endPage7047-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000378984600016-
dc.identifier.scopusid2-s2.0-84976638018-
dc.relation.journalWebOfScienceCategoryEngineering, Chemical-
dc.relation.journalResearchAreaEngineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusCATALYTIC-ACTIVITY-
dc.subject.keywordPlusEFFICIENT-
dc.subject.keywordPlusOXIDE-
dc.subject.keywordPlusDEHYDROGENATION-
dc.subject.keywordPlusBENZYLAMINES-
dc.subject.keywordPlusCOMPLEX-
dc.subject.keywordPlusOXYGEN-
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