Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | Hong, Sung Chul | - |
dc.contributor.author | Shin, Jeong Eun | - |
dc.contributor.author | Choi, Hee Jung | - |
dc.contributor.author | Gong, Hee Hyun | - |
dc.contributor.author | Kim, Kyungkon | - |
dc.contributor.author | Park, Nam-Gyu | - |
dc.date.accessioned | 2024-01-20T18:04:26Z | - |
dc.date.available | 2024-01-20T18:04:26Z | - |
dc.date.created | 2021-09-05 | - |
dc.date.issued | 2010-11-17 | - |
dc.identifier.issn | 0888-5885 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/130917 | - |
dc.description.abstract | A well-defined styrenic block copolymer was prepared through controlled/"living" radical polymerization technique and evaluated as a polymeric surface modifier for multiwalled carbon nanotube (MWCNT) in alpha-terpineol-based paste. First, poly(maleic anhydride-co-p-acetoxystyrene)-block-poly(p-acetoxystyrene) copolymer was prepared through a nitroxide-mediated polymerization (NMP) technique in an efficient "one-pot" reaction. The copolymer was then functionalized with pyretic; through an imidization reaction (SPM). Finally, p-acetoxystyrene units were converted to p-hydroxystyrene units through hydrolysis, affording pyrene-functionalized poly(maleic acid-co-p-hydroxystyrene)-block-poly(p-hydroxystyrene) (HSPM). Pyrene units in one block afforded efficient attachment points to the surface of MWCNT through pi-pi interaction, while polyp-hydroxystyrene) or poly(p-acetoxystyrene) tails afforded enhanced affinities With alpha-terpineol, as predicted by Hansen solubility parameter theory. Fabrications of electrodes through screen printing procedures employing MWCNT/HSPM or MWCNT/SPM pastes were facilitated through the surface modification of MWCNTs with the block copolymers, as evidenced by low viscosity, more homogeneous and smooth pastes, homogeneous/uniform MWCNT coatings, and low sheet resistance of the electrode. | - |
dc.language | English | - |
dc.publisher | AMER CHEMICAL SOC | - |
dc.subject | NONCOVALENT SIDEWALL-FUNCTIONALIZATION | - |
dc.subject | PYRENE | - |
dc.subject | POLYMERIZATION | - |
dc.subject | SOLUBILITY | - |
dc.subject | FILMS | - |
dc.title | Prediction and Evaluation of Styrenic Block Copolymers as Surface Modifiers for Multiwalled Carbon Nanotubes in alpha-Terpineol-Based Pastes | - |
dc.type | Article | - |
dc.identifier.doi | 10.1021/ie1013822 | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.49, no.22, pp.11393 - 11401 | - |
dc.citation.title | INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | - |
dc.citation.volume | 49 | - |
dc.citation.number | 22 | - |
dc.citation.startPage | 11393 | - |
dc.citation.endPage | 11401 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | 000283916700033 | - |
dc.identifier.scopusid | 2-s2.0-78449291449 | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.relation.journalResearchArea | Engineering | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | NONCOVALENT SIDEWALL-FUNCTIONALIZATION | - |
dc.subject.keywordPlus | PYRENE | - |
dc.subject.keywordPlus | POLYMERIZATION | - |
dc.subject.keywordPlus | SOLUBILITY | - |
dc.subject.keywordPlus | FILMS | - |
dc.subject.keywordAuthor | 염료감응형 태양전지 | - |
dc.subject.keywordAuthor | dye-sensitized solar cell | - |
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