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dc.contributor.authorHong, Sung Chul-
dc.contributor.authorShin, Jeong Eun-
dc.contributor.authorChoi, Hee Jung-
dc.contributor.authorGong, Hee Hyun-
dc.contributor.authorKim, Kyungkon-
dc.contributor.authorPark, Nam-Gyu-
dc.date.accessioned2024-01-20T18:04:26Z-
dc.date.available2024-01-20T18:04:26Z-
dc.date.created2021-09-05-
dc.date.issued2010-11-17-
dc.identifier.issn0888-5885-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/130917-
dc.description.abstractA well-defined styrenic block copolymer was prepared through controlled/"living" radical polymerization technique and evaluated as a polymeric surface modifier for multiwalled carbon nanotube (MWCNT) in alpha-terpineol-based paste. First, poly(maleic anhydride-co-p-acetoxystyrene)-block-poly(p-acetoxystyrene) copolymer was prepared through a nitroxide-mediated polymerization (NMP) technique in an efficient "one-pot" reaction. The copolymer was then functionalized with pyretic; through an imidization reaction (SPM). Finally, p-acetoxystyrene units were converted to p-hydroxystyrene units through hydrolysis, affording pyrene-functionalized poly(maleic acid-co-p-hydroxystyrene)-block-poly(p-hydroxystyrene) (HSPM). Pyrene units in one block afforded efficient attachment points to the surface of MWCNT through pi-pi interaction, while polyp-hydroxystyrene) or poly(p-acetoxystyrene) tails afforded enhanced affinities With alpha-terpineol, as predicted by Hansen solubility parameter theory. Fabrications of electrodes through screen printing procedures employing MWCNT/HSPM or MWCNT/SPM pastes were facilitated through the surface modification of MWCNTs with the block copolymers, as evidenced by low viscosity, more homogeneous and smooth pastes, homogeneous/uniform MWCNT coatings, and low sheet resistance of the electrode.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectNONCOVALENT SIDEWALL-FUNCTIONALIZATION-
dc.subjectPYRENE-
dc.subjectPOLYMERIZATION-
dc.subjectSOLUBILITY-
dc.subjectFILMS-
dc.titlePrediction and Evaluation of Styrenic Block Copolymers as Surface Modifiers for Multiwalled Carbon Nanotubes in alpha-Terpineol-Based Pastes-
dc.typeArticle-
dc.identifier.doi10.1021/ie1013822-
dc.description.journalClass1-
dc.identifier.bibliographicCitationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, v.49, no.22, pp.11393 - 11401-
dc.citation.titleINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH-
dc.citation.volume49-
dc.citation.number22-
dc.citation.startPage11393-
dc.citation.endPage11401-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000283916700033-
dc.identifier.scopusid2-s2.0-78449291449-
dc.relation.journalWebOfScienceCategoryEngineering, Chemical-
dc.relation.journalResearchAreaEngineering-
dc.type.docTypeArticle-
dc.subject.keywordPlusNONCOVALENT SIDEWALL-FUNCTIONALIZATION-
dc.subject.keywordPlusPYRENE-
dc.subject.keywordPlusPOLYMERIZATION-
dc.subject.keywordPlusSOLUBILITY-
dc.subject.keywordPlusFILMS-
dc.subject.keywordAuthor염료감응형 태양전지-
dc.subject.keywordAuthordye-sensitized solar cell-
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