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dc.contributor.authorSasamori, Takahiro-
dc.contributor.authorHan, Joon Soo-
dc.contributor.authorHironaka, Koji-
dc.contributor.authorTakagi, Nozomi-
dc.contributor.authorNagase, Shigeru-
dc.contributor.authorTokitoh, Norihiro-
dc.date.accessioned2024-01-20T20:00:23Z-
dc.date.available2024-01-20T20:00:23Z-
dc.date.created2021-09-01-
dc.date.issued2010-03-
dc.identifier.issn0033-4545-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/131701-
dc.description.abstractA novel 1,2-diaryldisilyne, BbtSi SiBbt (Bbt = 2,6-bis[bis(trimethylsilyl)methyl]-4-[tris(trimethylsilyl)methyl]phenyl), was synthesized as a stable compound by reduction of the corresponding 1,2-dibromodisilene, Bbt(Br)Si=Si(Br)Bbt. The spectral and structural features of this first stable 1,2-diaryldisilyne are revealed, and the Si Si triple-bond character is evaluated with the aid of detailed theoretical calculations. The triple-bond characters of BbtSi SiBbt and BbtGe GeBbt are compared based on experimental and theoretical results.-
dc.languageEnglish-
dc.publisherWALTER DE GRUYTER GMBH-
dc.subjectSILICON TRIPLE BOND-
dc.subjectELEMENT ALKYNE ANALOGS-
dc.subjectLOW COORDINATION-
dc.subjectMETAL ALKYLS-
dc.subjectLEAD ANALOGS-
dc.subjectCHEMISTRY-
dc.subjectDISILYNE-
dc.subjectTIN-
dc.subjectCOMPOUND-
dc.subjectSI-
dc.titleSynthesis and structure of stable 1,2-diaryldisilyne-
dc.typeArticle-
dc.identifier.doi10.1351/PAC-CON-09-08-02-
dc.description.journalClass1-
dc.identifier.bibliographicCitationPURE AND APPLIED CHEMISTRY, v.82, no.3, pp.603 - 612-
dc.citation.titlePURE AND APPLIED CHEMISTRY-
dc.citation.volume82-
dc.citation.number3-
dc.citation.startPage603-
dc.citation.endPage612-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000276000200011-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle; Proceedings Paper-
dc.subject.keywordPlusSILICON TRIPLE BOND-
dc.subject.keywordPlusELEMENT ALKYNE ANALOGS-
dc.subject.keywordPlusLOW COORDINATION-
dc.subject.keywordPlusMETAL ALKYLS-
dc.subject.keywordPlusLEAD ANALOGS-
dc.subject.keywordPlusCHEMISTRY-
dc.subject.keywordPlusDISILYNE-
dc.subject.keywordPlusTIN-
dc.subject.keywordPlusCOMPOUND-
dc.subject.keywordPlusSI-
dc.subject.keywordAuthordibromodisilene-
dc.subject.keywordAuthordigermyne-
dc.subject.keywordAuthordisilyne-
dc.subject.keywordAuthorkinetic stabilization-
dc.subject.keywordAuthortriple bond-
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