The effect of water on direct ethanol molten carbonate fuel cell

Authors
Devianto, HaryLi, ZhenlanYoon, Sung PilHan, JongheeNam, Suk-WooLim, Tae-HoonLee, Ho-In
Issue Date
2009-08-15
Publisher
ELSEVIER
Citation
CATALYSIS TODAY, v.146, no.1-2, pp.2 - 8
Abstract
Bio-ethanol can be used directly as a fuel in molten carbonate fuel cell (MCFC). Unfortunately, the high water content of bio-ethanol has several negative effects; decrease in performance, electrolyte loss due to evaporation, and corrosion of anode cell frame. This research was conducted to overcome the negative effects without degrading MCFC's performance and stability. A decrease in performance due to low H-2 An electrolyte loss was minimized when the recycling method was used. The contents was unavoidable. optimum recycling ratio was achieved when the flow rate ratio of output to recycle was in the range of 0.7-1. A corrosion of the cell frame was successfully blocked by Ni-electroplated cell frame. This system was successfully tested for over 2000 h without any decrease in performance. (C) 2009 Elsevier B.V. All rights reserved.
Keywords
SURFACE CHARACTERIZATION METHODS; BIPOLAR PLATE MATERIALS; HYDROGEN-PRODUCTION; CORROSION BEHAVIOR; GAS SHIFT; PART I; CATALYSTS; SYSTEM; PERFORMANCES; ISSUES; SURFACE CHARACTERIZATION METHODS; BIPOLAR PLATE MATERIALS; HYDROGEN-PRODUCTION; CORROSION BEHAVIOR; GAS SHIFT; PART I; CATALYSTS; SYSTEM; PERFORMANCES; ISSUES; MCFC; Ethanol; Water effect; Recycling; Corrosion
ISSN
0920-5861
URI
https://pubs.kist.re.kr/handle/201004/132237
DOI
10.1016/j.cattod.2008.12.017
Appears in Collections:
KIST Article > 2009
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