Octanol-accelerated Baylis-Hillman reaction

Authors
Park, Kwang-SuKim, JinyoungChoo, HyunahChong, Youhoon
Issue Date
2007-02-15
Publisher
GEORG THIEME VERLAG KG
Citation
SYNLETT, no.3, pp.395 - 398
Abstract
The Baylis-Hillman reaction was greatly accelerated by use of octanol as an additive. Under the octanol-accelerated Baylis-Hillman conditions, unactivated aldehydes such as aliphatic aldehydes and aromatic aldehydes with electron-withdrawing substituents were readily converted into the desired products in good to high yields.
Keywords
TITANIUM(IV) CHLORIDE; CARBONYL-COMPOUNDS; RATE ENHANCEMENT; ALDOL REACTIONS; LEWIS-BASE; ALDEHYDES; KETONES; ESTERS; TITANIUM(IV) CHLORIDE; CARBONYL-COMPOUNDS; RATE ENHANCEMENT; ALDOL REACTIONS; LEWIS-BASE; ALDEHYDES; KETONES; ESTERS; Baylis-Hillman reaction; octanol; additive; rate acceleration; aliphatic aldehydes
ISSN
0936-5214
URI
https://pubs.kist.re.kr/handle/201004/134644
DOI
10.1055/s-2007-968032
Appears in Collections:
KIST Article > 2007
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