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A semisynthesis of isepamicin by fragmentation method

Authors
Moon, MS; Jun, SJ; Lee, SH; Cheong, CS; Kim, KS; Lee, BS
Issue Date
2005-01-24
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON LETTERS, v.46, no.4, pp.607 - 609
Abstract
Garamine derivative, key intermediate, was obtained from acid cleavage of sisomicin derivative. Its subsequent product was glycosylated with 6-azido-2,3,4-tri-O-benzyl-6-deoxy-alpha-D-glucopyranosyl chloride using silver triflate as a promoter to give isepamicin. (C) 2004 Elsevier Ltd. All rights reserved.
Keywords
PROTECTED GARAMINE DERIVATIVES; BIOLOGICAL-ACTIVITY; GENTAMICIN-B; ANTIBIOTICS; PROTECTED GARAMINE DERIVATIVES; BIOLOGICAL-ACTIVITY; GENTAMICIN-B; ANTIBIOTICS; garamine; iseparnicin; aminoglycoside; antibiotics
ISSN
0040-4039
URI
https://pubs.kist.re.kr/handle/201004/136817
DOI
10.1016/j.tetlet.2004.11.130
Appears in Collections:
KIST Article > 2005
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