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dc.contributor.authorKim, EJ-
dc.contributor.authorKo, SY-
dc.contributor.authorSong, CE-
dc.date.accessioned2024-01-21T09:13:33Z-
dc.date.available2024-01-21T09:13:33Z-
dc.date.created2021-09-01-
dc.date.issued2003-03-
dc.identifier.issn0018-019X-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/138809-
dc.description.abstractThe Baylis-Hillman reaction is accelerated in the presence of ionic liquids. Of various 1-butyl-3-methylimidazolium (bmim)-based ionic liquids tested, [bmim][PF6] has been found to result in the highest rate increase. In the company of Lewis acid and H-bond-donor additives, the reaction rates further improve, albeit only modestly. A preparatively useful Baylis-Hillman procedure prescribes the use of [bmim][PF6] with La(OTf)(3) and 2,2'2"-nitrilotris[ethanol], in which the net effect of the ionic liquid is to bring about a more than twofold rate increase over the otherwise same reaction in MeCN.-
dc.languageEnglish-
dc.publisherWILEY-V C H VERLAG GMBH-
dc.subjectRATE ENHANCEMENT-
dc.subjectCARBONYL-COMPOUNDS-
dc.subjectFIRST-EXAMPLES-
dc.subjectLEWIS-ACIDS-
dc.subjectTEMPERATURE-
dc.subjectCATALYSIS-
dc.subjectMETAL-
dc.subjectSOLVENTS-
dc.subjectSALTS-
dc.titleAcceleration of the Baylis-Hillman reaction in the presence of ionic liquids-
dc.typeArticle-
dc.identifier.doi10.1002/hlca.200390087-
dc.description.journalClass1-
dc.identifier.bibliographicCitationHELVETICA CHIMICA ACTA, v.86, no.3, pp.894 - 899-
dc.citation.titleHELVETICA CHIMICA ACTA-
dc.citation.volume86-
dc.citation.number3-
dc.citation.startPage894-
dc.citation.endPage899-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000182095900034-
dc.identifier.scopusid2-s2.0-0037260458-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusRATE ENHANCEMENT-
dc.subject.keywordPlusCARBONYL-COMPOUNDS-
dc.subject.keywordPlusFIRST-EXAMPLES-
dc.subject.keywordPlusLEWIS-ACIDS-
dc.subject.keywordPlusTEMPERATURE-
dc.subject.keywordPlusCATALYSIS-
dc.subject.keywordPlusMETAL-
dc.subject.keywordPlusSOLVENTS-
dc.subject.keywordPlusSALTS-
dc.subject.keywordAuthorBaylis-Hillman reaction-
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