DSpace at KISTKIST Article2001

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dc.contributor.authorKim, SJ-
dc.contributor.authorJung, IN-
dc.contributor.authorYoo, BR-
dc.contributor.authorCho, S-
dc.contributor.authorKo, J-
dc.contributor.authorKim, SH-
dc.contributor.authorKang, SO-
dc.date.accessioned2024-01-21T12:33:04Z-
dc.date.available2024-01-21T12:33:04Z-
dc.date.created2021-09-04-
dc.date.issued2001-04-16-
dc.identifier.issn0276-7333-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/140527-
dc.description.abstractThe reaction between the spirosiladiazatitanacyclobutane complexes (cyclo)Si(NBut)(2)TiMe2 (1) and (cyclo)Si(NBut)(2)TiMeCl (3a) and dioxygen proceeds by insertion of an oxygen molecule into a Ti-C bond of 1 and 3a, yielding methoxy-bridged titanium dimer [(cyclo)Si(NBut)(2)Ti(mu -OMe)Me](2) (2) or [(cyclo)Si(NBut)2Ti(mu -OMe)Cl](2) 4a), respectively. In contrast, the reaction of the titanium(IV) dichloride complex (cyclo)Si(NBut)(2)-TiCl2 (5a) with O-2 gives hydrazido complete [{((NBuNBut)-N-t-(cyclo)SiO}TiCl2](2) (6a) as a result of facile formation of the Si-O-Ti bonds upon autoxidation.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMOLECULAR-STRUCTURE-
dc.subjectZIRCONIUM COMPLEXES-
dc.subjectDINITROGEN RESIDUES-
dc.subjectCRYSTAL-STRUCTURES-
dc.subjectGROUP-4-
dc.subjectPOLYMERIZATION-
dc.subjectDERIVATIVES-
dc.subjectREACTIVITY-
dc.subjectDIAMIDE-
dc.subjectOXYGEN-
dc.titleFacile generation of bimetallic titanium alkoxides with silacycloalkyl- or silacycloalkenyldiamide ligands: Oxo-insertion involving dimerization or rearrangement-
dc.typeArticle-
dc.identifier.doi10.1021/om000955q-
dc.description.journalClass1-
dc.identifier.bibliographicCitationORGANOMETALLICS, v.20, no.8, pp.1501 - 1503-
dc.citation.titleORGANOMETALLICS-
dc.citation.volume20-
dc.citation.number8-
dc.citation.startPage1501-
dc.citation.endPage1503-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000168395000004-
dc.identifier.scopusid2-s2.0-0035897437-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusMOLECULAR-STRUCTURE-
dc.subject.keywordPlusZIRCONIUM COMPLEXES-
dc.subject.keywordPlusDINITROGEN RESIDUES-
dc.subject.keywordPlusCRYSTAL-STRUCTURES-
dc.subject.keywordPlusGROUP-4-
dc.subject.keywordPlusPOLYMERIZATION-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusREACTIVITY-
dc.subject.keywordPlusDIAMIDE-
dc.subject.keywordPlusOXYGEN-
dc.subject.keywordAuthorsilicon-
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