Immobilisation of ketone catalyst: a method to prevent ketone catalyst from decomposing during dioxirane-mediated epoxidation of alkenes
- Authors
- Song, CE; Lim, JS; Kim, SC; Lee, KJ; Chi, DY
- Issue Date
- 2000-12
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, no.24, pp.2415 - 2416
- Abstract
- Covalent attachment of trifluoromethyl ketone catalyst to a solid support such as silica gel increased the stability of catalyst dramatically, so solving an intrinsic problem of dioxirane-mediated epoxidation of alkenes catalysed by ketones.
- Keywords
- CHIRAL STATIONARY PHASES; CINCHONA ALKALOIDS; SILICA; OXIDATIONS; CHEMISTRY; OXIDANTS; OLEFINS; CHIRAL STATIONARY PHASES; CINCHONA ALKALOIDS; SILICA; OXIDATIONS; CHEMISTRY; OXIDANTS; OLEFINS; immobilization; ketone catalyst; dioxirane; epoxidation; oxone
- ISSN
- 1359-7345
- URI
- https://pubs.kist.re.kr/handle/201004/140905
- DOI
- 10.1039/b005604i
- Appears in Collections:
- KIST Article > 2000
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