Indium and tin mediated allylation reactions of 3-hydroxycephem in aqueous media
- Authors
- Lee, JE; Cha, JH; Pae, AN; Choi, KI; Koh, HY; Kim, Y; Cho, YS
- Issue Date
- 2000-12
- Publisher
- MARCEL DEKKER INC
- Citation
- SYNTHETIC COMMUNICATIONS, v.30, no.23, pp.4299 - 4308
- Abstract
- Allylation of the C-3 position of the cephem nucleus was accomplished by either indium mediated or indium trichloride promoted tin mediated allylation reactions in aqueous media. Both methods gave 3-allyl-3-hydroxycephams 2a similar to 2d, in moderate to excellent yields.
- Keywords
- CEPHEM SIDE-CHAINS; CEPHALOSPORIN CHEMISTRY; PALLADIUM; CEPHEM SIDE-CHAINS; CEPHALOSPORIN CHEMISTRY; PALLADIUM; indium
- ISSN
- 0039-7911
- URI
- https://pubs.kist.re.kr/handle/201004/140914
- DOI
- 10.1080/00397910008087052
- Appears in Collections:
- KIST Article > 2000
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