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dc.contributor.authorKang, JY-
dc.contributor.authorKim, HY-
dc.contributor.authorKim, JH-
dc.date.accessioned2024-01-21T15:12:31Z-
dc.date.available2024-01-21T15:12:31Z-
dc.date.created2021-09-05-
dc.date.issued1999-07-02-
dc.identifier.issn0957-4166-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/142054-
dc.description.abstractEnantiomerically pure pyridyl alcohols, 1 and 2, were prepared from readily available racemic pyridyl alcohol 3 and applied to the enantioselective addition of diethylzinc to aldehydes resulting in moderately high enantiomeric excess (90%) in the case of benzaldehyde. In this study the first example of an alteration in the configuration of the product upon change of a non-chiral and non-coordinating part of the catalyst was observed. (C) 1999 Elsevier Science Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectHIGHLY DIASTEREOSELECTIVE REDUCTION-
dc.subjectALPHA-AMINO KETONE-
dc.subjectASYMMETRIC-SYNTHESIS-
dc.subjectSTEREOSPECIFIC ARYLATION-
dc.subjectORGANOZINC REAGENTS-
dc.subjectAROMATIC-ALDEHYDES-
dc.subjectCATALYSTS-
dc.subjectBENZALDEHYDE-
dc.subjectDIALKYLZINC-
dc.subjectLIGANDS-
dc.titleSynthesis of chiral plane-extended pyridyl alcohols for the enantioselective addition of diethylzinc to aldehydes-
dc.typeArticle-
dc.identifier.doi10.1016/S0957-4166(99)00247-5-
dc.description.journalClass1-
dc.identifier.bibliographicCitationTETRAHEDRON-ASYMMETRY, v.10, no.13, pp.2523 - 2533-
dc.citation.titleTETRAHEDRON-ASYMMETRY-
dc.citation.volume10-
dc.citation.number13-
dc.citation.startPage2523-
dc.citation.endPage2533-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000082102000007-
dc.identifier.scopusid2-s2.0-0033516447-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusHIGHLY DIASTEREOSELECTIVE REDUCTION-
dc.subject.keywordPlusALPHA-AMINO KETONE-
dc.subject.keywordPlusASYMMETRIC-SYNTHESIS-
dc.subject.keywordPlusSTEREOSPECIFIC ARYLATION-
dc.subject.keywordPlusORGANOZINC REAGENTS-
dc.subject.keywordPlusAROMATIC-ALDEHYDES-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusBENZALDEHYDE-
dc.subject.keywordPlusDIALKYLZINC-
dc.subject.keywordPlusLIGANDS-
dc.subject.keywordAuthorchiral-
dc.subject.keywordAuthorpyridyl alcohols-
dc.subject.keywordAuthorenantioselective addition-
dc.subject.keywordAuthordiethylzinc-
dc.subject.keywordAuthoraldehyde-
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