Spectroscopic measurement of the acid dissociation constant of 2-naphthol and the second dissociation constant of carbonic acid at elevated temperatures

Abstract

2-Naphthol can be used to measure the pH of aqueous solutions if the acid dissociation constant for 2-naphthol is known at a given temperature. The temperature dependence of the acid dissociation constant for 2-naphthol was spectroscopically determined in berate buffer solutions under vapor-saturated pressure up to 200 degrees C. The result was pK(i) = -34.97 + 2947/T + 6.086 ln(T) where T is in Kelvin. The pH of carbonate buffer solutions was measured by obtaining the W-visible spectra of 2-naphthol and utilized to determine the second dissociation constant of carbonic acid up to 175 degrees C under vapor-saturated pressure. The result was pK(2) = 4201.48 - 229 200/T 661.21 ln(T) + 0647.53T + 134 98 200/T-2 where T is in Kelvin. By using the temperature dependence of the dissociation constant, the isocoulombic reaction was studied. The plot of - log K-isoc against 1/T was approximately linear in the temperature range studied. The linearity can be used to predict the dissociation constant by the extrapolation of -log K-isoc to higher temperatures.