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dc.contributor.authorMoon, DJ-
dc.contributor.authorChung, MJ-
dc.contributor.authorPark, KY-
dc.contributor.authorHong, SI-
dc.date.accessioned2024-01-21T16:11:17Z-
dc.date.available2024-01-21T16:11:17Z-
dc.date.created2021-09-03-
dc.date.issued1999-01-
dc.identifier.issn0008-6223-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/142602-
dc.description.abstractAdsorption equilibria of chloropentafluoroethane (CF3CF2Cl, CFC-115) on Pd/activated carbon powder and on activated carbon powder were examined between 298.15 and 373.15 K. The adsorption equilibria of CFC-115 on the Pd/activated carbon powder and the activated carbon powder can be well represented by the BET equation. The isosteric heats of adsorption of CFC-115 on both adsorbents are of approximately the same order of magnitude as the heats of condensation. This means that the adsorption of CFC-115 on both adsorbents is primarily due to physical forces. By hydrodechlorination over the Pd/activated carbon powder, CFC-115 could be converted to pentafluoroethane (CF3CF2H, HFC-125) with more than 99% selectivity. It was found that the Pd/activated carbon powder can be used as an adsorbent for recovering CFC-115 and a catalyst for manufacturing HFC-125 from CFC-115. (C) 1998 Elsevier Science Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectSILICA-GEL-
dc.subjectCHLOROFLUOROMETHANES-
dc.subjectDESTRUCTION-
dc.subjectOZONE-
dc.titleAdsorption equilibrium and catalytic reaction of CFC-115 on Pd/activated carbon powder-
dc.typeArticle-
dc.identifier.doi10.1016/S0008-6223(98)00196-1-
dc.description.journalClass1-
dc.identifier.bibliographicCitationCARBON, v.37, no.1, pp.123 - 128-
dc.citation.titleCARBON-
dc.citation.volume37-
dc.citation.number1-
dc.citation.startPage123-
dc.citation.endPage128-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000077889100017-
dc.identifier.scopusid2-s2.0-0032793859-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalWebOfScienceCategoryMaterials Science, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.relation.journalResearchAreaMaterials Science-
dc.type.docTypeArticle-
dc.subject.keywordPlusSILICA-GEL-
dc.subject.keywordPlusCHLOROFLUOROMETHANES-
dc.subject.keywordPlusDESTRUCTION-
dc.subject.keywordPlusOZONE-
dc.subject.keywordAuthoractivated carbon-
dc.subject.keywordAuthoradsorption properties-
dc.subject.keywordAuthorCFC-115-
dc.subject.keywordAuthorhydrodechlorination-
dc.subject.keywordAuthorHFC-125-
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