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dc.contributor.authorRyu, SY-
dc.contributor.authorYang, W-
dc.contributor.authorKim, HS-
dc.contributor.authorPark, S-
dc.date.accessioned2024-01-21T17:45:52Z-
dc.date.available2024-01-21T17:45:52Z-
dc.date.created2021-09-05-
dc.date.issued1997-11-20-
dc.identifier.issn0253-2964-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/143503-
dc.description.abstractDimethylamine complexes of palladium(II) [(PCP)Pd(NHMe2)](OTf) (PCP = 2,6-(R2PCH2)(2)C6H3); R = Ph (1), R = Cy (2)), have been prepared from the reaction of (PCP)Pd(OTf) and dimethylamine. The complex 1 is stable both in solution and in the solid state, while 2 is stable only in-solution in the presence of dimethylamine although the formation of 2 in solution is quantitative by NMR spectroscopy. A solution NMR spectroscopic study shows that dimethylamine favors over carbon monoxide in the coordination sphere of palladium(II) having rigid terdentate ligands. The complexes 1 and 2 in chlorinated solvents undergo a chlorine abstract reaction yielding Pd(2,6-(R2PCH2)(2)C6H3)Cl in the presence of a base such as dimethylamine and DAB-CO (diazabicyclooctane), in which a transient dimethylamido palladium(II) species likely involves.-
dc.languageEnglish-
dc.publisherKOREAN CHEMICAL SOC-
dc.subjectMETAL-
dc.subjectCATALYSTS-
dc.subjectAMIDES-
dc.subjectAMINES-
dc.titleFormation and properties of dimethylamine complexes of palladium(II) having trans phosphorus spanning terdentate ligands.-
dc.typeArticle-
dc.description.journalClass1-
dc.identifier.bibliographicCitationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.18, no.11, pp.1183 - 1185-
dc.citation.titleBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.citation.volume18-
dc.citation.number11-
dc.citation.startPage1183-
dc.citation.endPage1185-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosidA1997YJ28500017-
dc.identifier.scopusid2-s2.0-0642334710-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusMETAL-
dc.subject.keywordPlusCATALYSTS-
dc.subject.keywordPlusAMIDES-
dc.subject.keywordPlusAMINES-
dc.subject.keywordAuthorpalladium dimethylamine complex-
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