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dc.contributor.authorLee, S-
dc.contributor.authorLim, CW-
dc.contributor.authorSong, CE-
dc.contributor.authorKim, IO-
dc.contributor.authorJun, CH-
dc.date.accessioned2024-01-21T18:04:33Z-
dc.date.available2024-01-21T18:04:33Z-
dc.date.created2021-09-05-
dc.date.issued1997-09-11-
dc.identifier.issn0957-4166-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/143592-
dc.description.abstractNew C-2-symmetric chiral (4S,4'S)-bioxazoles 3a and 3b, possessing chirality on their backbone, were synthesized efficiently starting from L-tartaric acid. The structure of 3a was determined by X-ray crystal structure analysis. With these novel chiral bioxazole ligands, as a preliminary investigation for their effects on the enantioselectivity, rhodium(I)-catalyzed enantioselective hydrosilylations of acetophenone were carried out. (C) 1997 Published by Elsevier Science Ltd.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectCATALYZED ALLYLIC SUBSTITUTION-
dc.subjectPHOSPHINE HYBRID LIGAND-
dc.subjectENANTIOSELECTIVE HYDROSILYLATION-
dc.subjectOXAZOLINE LIGANDS-
dc.subjectCYCLOPROPANATION-
dc.subjectKETONES-
dc.subjectOLEFINS-
dc.subjectCOMPLEXES-
dc.titleSynthesis of new C-2-symmetsic bioxazoles and application as chiral ligands in asymmetric hydrosilylation-
dc.typeArticle-
dc.identifier.doi10.1016/S0957-4166(97)00353-4-
dc.description.journalClass1-
dc.identifier.bibliographicCitationTETRAHEDRON-ASYMMETRY, v.8, no.17, pp.2927 - 2932-
dc.citation.titleTETRAHEDRON-ASYMMETRY-
dc.citation.volume8-
dc.citation.number17-
dc.citation.startPage2927-
dc.citation.endPage2932-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosidA1997XY65700010-
dc.identifier.scopusid2-s2.0-0030864736-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusCATALYZED ALLYLIC SUBSTITUTION-
dc.subject.keywordPlusPHOSPHINE HYBRID LIGAND-
dc.subject.keywordPlusENANTIOSELECTIVE HYDROSILYLATION-
dc.subject.keywordPlusOXAZOLINE LIGANDS-
dc.subject.keywordPlusCYCLOPROPANATION-
dc.subject.keywordPlusKETONES-
dc.subject.keywordPlusOLEFINS-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordAuthorC ₂ -symmetric bioxazole ligand-
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