DSpace at KIST: Alkylations of functionalized organozinc reagents with allylic epoxides catalyzed by a cyanocuprate

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Alkylations of functionalized organozinc reagents with allylic epoxides catalyzed by a cyanocuprate

Authors: Lipshutz, BH; Woo, K; Gross, T; Buzard, DJ; Tirado, R

Issue Date: 1997-05

Publisher: GEORG THIEME VERLAG

Citation: SYNLETT, no.5, pp.477 - &

Abstract: Transmetalation of a functionalized organozinc reagent with 5-10 mol % Me2Cu(CN)Li-2 or MeCu(CN)Li leads to a cyanocuprate which selectively transfers the desired ligand in an S(N)2' sense to allylic epoxides.

Keywords: KETONES; KETONES; Cu(I)-catalyzed alkylations; mixed zinc reagents; transmetalations

ISSN: 0936-5214

URI: https://pubs.kist.re.kr/handle/201004/143836

Appears in Collections:: KIST Article > Others

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