Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.author | CHUNG, MJ | - |
dc.contributor.author | PARK, KY | - |
dc.contributor.author | LEE, BG | - |
dc.contributor.author | IHM, SK | - |
dc.date.accessioned | 2024-01-21T22:31:23Z | - |
dc.date.available | 2024-01-21T22:31:23Z | - |
dc.date.created | 2021-09-02 | - |
dc.date.issued | 1993-07 | - |
dc.identifier.issn | 0256-1115 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/146025 | - |
dc.description.abstract | The reaction mechanism for the methylformate formation on Cu/ZnO catalysts from methanol and CO was investigated by the labeling study with C-13 methanol. It was found that methylformate could be formed through two parallel reaction routes, i.e., methanol-formaldehyde reaction and carbonylation of methanol depending upon the catalyst composition as well as the reaction conditions. The major reaction route on the high ZnO-content catalyst (Cu/ZnO=30/70) was found to be the methanol-formaldehyde reaction, and changed to the carbonylation reaction with the increase of CO partial pressure. On the other hand, the major reaction route on the high Cu-content catalyst (Cu/ZnO=80/20) remained as methanol-formaldehyde reaction even under the high CO pressure. | - |
dc.language | English | - |
dc.publisher | KOREAN INST CHEM ENGINEERS | - |
dc.title | Methylformate formation from methanol and CO ON Cu/ZnO catalysts | - |
dc.type | Article | - |
dc.identifier.doi | 10.1007/BF02705142 | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | KOREAN JOURNAL OF CHEMICAL ENGINEERING, v.10, no.3, pp.188 - 190 | - |
dc.citation.title | KOREAN JOURNAL OF CHEMICAL ENGINEERING | - |
dc.citation.volume | 10 | - |
dc.citation.number | 3 | - |
dc.citation.startPage | 188 | - |
dc.citation.endPage | 190 | - |
dc.description.isOpenAccess | N | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | A1993MJ96700008 | - |
dc.identifier.scopusid | 2-s2.0-51649139804 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Multidisciplinary | - |
dc.relation.journalWebOfScienceCategory | Engineering, Chemical | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.relation.journalResearchArea | Engineering | - |
dc.type.docType | Note | - |
dc.subject.keywordAuthor | methylformate | - |
dc.subject.keywordAuthor | methanol | - |
dc.subject.keywordAuthor | carbon monoxide | - |
dc.subject.keywordAuthor | catalysis | - |
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