Mechanically Adaptable High-Performance p(SBMA-MMA) Copolymer Hydrogel with Iron (II/III) Perchlorate for Wearable Thermocell Applications

Authors
Shin, GilyongBaek, Jae YoonKim, Ju HyeonLee, Ju HwanKim, Hyeong JunSo, Byeong JunChoi, YuseungYun, SungryulKim, TaewooJeon, Jei GyeongKang, Tae June
Issue Date
2024-10
Publisher
John Wiley & Sons Ltd.
Citation
Advanced Functional Materials
Abstract
Quasi-solid-state thermocells (QTECs) show promise as a power source for wearable devices by converting body heat into electricity. While significant progress has been made with p-type elements for QTECs, challenges remain with their n-type counterparts. Here, a high-performance n-type QTEC element is presented, using a copolymer hydrogel that outperforms conventional p-type elements. This copolymer hydrogel combines hydrophilic zwitterionic sulfobetaine methacrylate (SBMA) for ionic conduction and hydrophobic methyl methacrylate (MMA) for structural stability. By increasing the MMA content from 35 to 100 wt.%, versatile control is achieved over the hydrogel's elastic modulus (72 kPa to 127.7 MPa) and tensile strength (54 kPa to 6.7 MPa). A high mechanical toughness of 7.2 MJ m-3 is also achieved at 68 wt.% MMA. The mechanically robust and high toughness p(SBMA-MMA) hydrogel is then immersed in Fe(ClO4)2/3 solutions of different concentrations to evaluate its performance as an n-type QTEC element. The hydrogel with 0.8 M Fe(ClO4)2/3 exhibits a high ionic Seebeck coefficient of -1.7 mV K-1, a power density of 1.1 mW m-2 K-2, and an elastic modulus of 1.6 MPa, which is similar to that of human skin. Finally, the optimized n-type p(SBMA-MMA) hydrogels demonstrate the potential application for wearable devices. A high-performance n-type element for quasi-solid-state thermocells has been introduced, outperforming conventional p-type elements and showcasing the potential to harness body heat as an energy source or power embedded sensors. This advance significantly contributes to waste thermal energy harvesting and wearable technology, paving the way for self-powered wearable devices. image
Keywords
IONS; THERMOGALVANIC CELLS; TOUGH; ELECTROLYTES; THERMOPOWER; STIFFNESS; hydrogel; iron (II/III) perchlorate; sulfobetaine methacrylate; thermocell; wearables
ISSN
1616-301X
URI
https://pubs.kist.re.kr/handle/201004/150997
DOI
10.1002/adfm.202412524
Appears in Collections:
KIST Article > 2024
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