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dc.contributor.authorKim, Sung-Kwan-
dc.contributor.authorHan, Won-Sik-
dc.contributor.authorKim, Tae-Jin-
dc.contributor.authorKim, Tae-Young-
dc.contributor.authorNam, Suk Woo-
dc.contributor.authorMitoraj, Mariusz-
dc.contributor.authorPiekos, Lukasz-
dc.contributor.authorMichalak, Artur-
dc.contributor.authorHwang, Son-Jong-
dc.contributor.authorKang, Sang Ook-
dc.date.accessioned2024-01-20T19:01:00Z-
dc.date.available2024-01-20T19:01:00Z-
dc.date.created2021-09-05-
dc.date.issued2010-07-28-
dc.identifier.issn0002-7863-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/131240-
dc.description.abstractCationic Pd(II) complexes catalyzed the dehydrogenation of ammonia borane in the most efficient manner with the release of 2.0 equiv of H-2 in less than 60 s at 25 degrees C. Most of the hydrogen atoms were obtained from the boron atom of the ammonia borane. The first step of the dehydrogenation reaction was elaborated using density functional theory calculations.-
dc.languageEnglish-
dc.publisherAMER CHEMICAL SOC-
dc.subjectMETAL-PROMOTED REACTIONS-
dc.subjectBORON-NITROGEN BONDS-
dc.subjectCOUPLED-CAGE BORANE-
dc.subjectAMINE-BORANE-
dc.subjectHYDRIDES-
dc.subjectAMINOBORANES-
dc.subjectCOMPLEXES-
dc.subjectCARBORANE-
dc.subjectNITRIDE-
dc.subjectROUTE-
dc.titlePalladium Catalysts for Dehydrogenation of Ammonia Borane with Preferential B-H Activation-
dc.typeArticle-
dc.identifier.doi10.1021/ja101685u-
dc.description.journalClass1-
dc.identifier.bibliographicCitationJOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.132, no.29, pp.9954 - 9955-
dc.citation.titleJOURNAL OF THE AMERICAN CHEMICAL SOCIETY-
dc.citation.volume132-
dc.citation.number29-
dc.citation.startPage9954-
dc.citation.endPage9955-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000280227700008-
dc.identifier.scopusid2-s2.0-77955832702-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusMETAL-PROMOTED REACTIONS-
dc.subject.keywordPlusBORON-NITROGEN BONDS-
dc.subject.keywordPlusCOUPLED-CAGE BORANE-
dc.subject.keywordPlusAMINE-BORANE-
dc.subject.keywordPlusHYDRIDES-
dc.subject.keywordPlusAMINOBORANES-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusCARBORANE-
dc.subject.keywordPlusNITRIDE-
dc.subject.keywordPlusROUTE-
dc.subject.keywordAuthorammonia borane-
dc.subject.keywordAuthordehydrogenation-
dc.subject.keywordAuthorPd(II) complexes-
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