Reaction products between TiCl3 catalyst and Li3AlH6 during mechanical mixing

Authors
Shim, Jae-HyeokLee, Gil-JaeCho, Young Whan
Issue Date
2006-08-10
Publisher
ELSEVIER SCIENCE SA
Citation
JOURNAL OF ALLOYS AND COMPOUNDS, v.419, no.1-2, pp.176 - 179
Abstract
The reaction between TiCl3 and LbAlH(6) was investigated to understand reaction products in Ti-catalyzed Li3AlH6 using mechanical milling and thermodynamic calculation. As reaction products, LiCl, TiAl3 and TiH2 are observed by X-ray powder diffraction, which is in agreement with the results of thermodynamic calculation. TiAl3 forms in an L1(2) structure rather than an equilibrium D0(22) structure during milling. It is predicted that the mole fraction of TiAl3 increases and that of TiH2 decreases as temperature increases during milling. Differential scanning calorimetry confirms that TiAl3 acts as a dehydrogenation catalyst in Li3AlH6. (c) 2005 Elsevier B.V. All rights reserved.
Keywords
REVERSIBLE HYDROGEN STORAGE; LIALH4; TRANSFORMATIONS; STABILITY; REVERSIBLE HYDROGEN STORAGE; LIALH4; TRANSFORMATIONS; STABILITY; energy storage materials; mechanochemical synthesis; X-ray diffraction; thermal analysis; hydrogen storage materials; catalyst
ISSN
0925-8388
URI
https://pubs.kist.re.kr/handle/201004/135246
DOI
10.1016/j.jallcom.2005.07.079
Appears in Collections:
KIST Article > 2006
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