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Indium-mediated coupling of bromoacetonitriles with aromatic acyl cyanides: convenient synthesis of aromatic alpha-cyano ketones

Authors
Yoo, BW; Hwang, SK; Kim, DY; Choi, JW; Ko, JJ; Choi, KI; Kim, JH
Issue Date
2002-07-01
Publisher
PERGAMON-ELSEVIER SCIENCE LTD
Citation
TETRAHEDRON LETTERS, v.43, no.27, pp.4813 - 4815
Abstract
Indium-mediated coupling of bromoacetonitrile and 2-bromopropionitrile with a variety of aromatic acyl cyanides afforded the corresponding aromatic alpha-cyano ketones in moderate to good yields under mild and neutral conditions. (C) 2002 Elsevier Science Ltd. All rights reserved.
Keywords
BETA-HYDROXY NITRILES; HOMOALLYLIC AMINES; ENANTIOSELECTIVE SYNTHESIS; PROP-2-YNYL BROMIDES; REFORMATSKY REACTION; FACILE SYNTHESIS; AQUEOUS-MEDIA; ALDEHYDES; ALLYLATION; PROPARGYLATION; BETA-HYDROXY NITRILES; HOMOALLYLIC AMINES; ENANTIOSELECTIVE SYNTHESIS; PROP-2-YNYL BROMIDES; REFORMATSKY REACTION; FACILE SYNTHESIS; AQUEOUS-MEDIA; ALDEHYDES; ALLYLATION; PROPARGYLATION; acyl cyanide; coupling; indium and compounds; cyano ketone
ISSN
0040-4039
URI
https://pubs.kist.re.kr/handle/201004/139382
DOI
10.1016/S0040-4039(02)00925-5
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KIST Article > 2002
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