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DSpace at KISTKIST Article 2001

Halogenation of aromatic methyl ketones using Oxone (R) and sodium halide

Authors: Kim, EH; Koo, BS; Song, CE; Lee, KJ

Issue Date: 2001-11

Publisher: MARCEL DEKKER INC

Citation: SYNTHETIC COMMUNICATIONS, v.31, no.23, pp.3627 - 3632

Abstract: Aromatic methyl ketones undergo alpha -halogenation on treatment with sodium halide in the presence of oxone (R) in aqueous methanol. However, electron-rich hetero aromatic methyl ketones afford ring bromination products preferentially.

Keywords: OXIDATIVE CLEAVAGE; PEPTIDE-SYNTHESIS; DIOXIRANE; CARBONYL; OXIDATIVE CLEAVAGE; PEPTIDE-SYNTHESIS; DIOXIRANE; CARBONYL; halogenation

ISSN: 0039-7911

URI: https://pubs.kist.re.kr/handle/201004/140089

DOI: 10.1081/SCC-100107011

Appears in Collections:: KIST Article > 2001

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