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dc.contributor.authorShin, JA-
dc.contributor.authorCha, JH-
dc.contributor.authorPae, AN-
dc.contributor.authorChoi, KI-
dc.contributor.authorKoh, HY-
dc.contributor.authorKang, HY-
dc.contributor.authorCho, YS-
dc.date.accessioned2024-01-21T12:02:25Z-
dc.date.available2024-01-21T12:02:25Z-
dc.date.created2021-09-05-
dc.date.issued2001-08-06-
dc.identifier.issn0040-4039-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/140245-
dc.description.abstractIndium-mediated allylation reactions of alpha-ketoimides derived from Oppolzer's sultam were accomplished in aqueous THF in good yields and excellent diastereomeric excesses. It could be a useful method for the preparation of enantiopure t-alpha -hydroxy acids. When the substituent of alpha-ketoimides was changed from phenyl to thiophenyl or furyl group, diastereoselectivity decreased in comparison to N-phenyl derivatives, but changing solvent to aqueous ethanol provided improved levels of diastereo selectivity. (C) 2001 Elsevier Science Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectENANTIOSELECTIVE SYNTHESIS-
dc.subjectOXOCARBOXYLIC ACIDS-
dc.titleIndium-mediated diastereoselective allylation reactions: preparation of tert-alpha-hydroxy acids-
dc.typeArticle-
dc.identifier.doi10.1016/S0040-4039(01)01064-4-
dc.description.journalClass1-
dc.identifier.bibliographicCitationTETRAHEDRON LETTERS, v.42, no.32, pp.5489 - 5492-
dc.citation.titleTETRAHEDRON LETTERS-
dc.citation.volume42-
dc.citation.number32-
dc.citation.startPage5489-
dc.citation.endPage5492-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000170127200039-
dc.identifier.scopusid2-s2.0-0035817350-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusENANTIOSELECTIVE SYNTHESIS-
dc.subject.keywordPlusOXOCARBOXYLIC ACIDS-
dc.subject.keywordAuthorindium-mediated-
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KIST Article > 2001
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