Full metadata record
DC Field | Value | Language |
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dc.contributor.author | Shin, JA | - |
dc.contributor.author | Cha, JH | - |
dc.contributor.author | Pae, AN | - |
dc.contributor.author | Choi, KI | - |
dc.contributor.author | Koh, HY | - |
dc.contributor.author | Kang, HY | - |
dc.contributor.author | Cho, YS | - |
dc.date.accessioned | 2024-01-21T12:02:25Z | - |
dc.date.available | 2024-01-21T12:02:25Z | - |
dc.date.created | 2021-09-05 | - |
dc.date.issued | 2001-08-06 | - |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | https://pubs.kist.re.kr/handle/201004/140245 | - |
dc.description.abstract | Indium-mediated allylation reactions of alpha-ketoimides derived from Oppolzer's sultam were accomplished in aqueous THF in good yields and excellent diastereomeric excesses. It could be a useful method for the preparation of enantiopure t-alpha -hydroxy acids. When the substituent of alpha-ketoimides was changed from phenyl to thiophenyl or furyl group, diastereoselectivity decreased in comparison to N-phenyl derivatives, but changing solvent to aqueous ethanol provided improved levels of diastereo selectivity. (C) 2001 Elsevier Science Ltd. All rights reserved. | - |
dc.language | English | - |
dc.publisher | PERGAMON-ELSEVIER SCIENCE LTD | - |
dc.subject | ENANTIOSELECTIVE SYNTHESIS | - |
dc.subject | OXOCARBOXYLIC ACIDS | - |
dc.title | Indium-mediated diastereoselective allylation reactions: preparation of tert-alpha-hydroxy acids | - |
dc.type | Article | - |
dc.identifier.doi | 10.1016/S0040-4039(01)01064-4 | - |
dc.description.journalClass | 1 | - |
dc.identifier.bibliographicCitation | TETRAHEDRON LETTERS, v.42, no.32, pp.5489 - 5492 | - |
dc.citation.title | TETRAHEDRON LETTERS | - |
dc.citation.volume | 42 | - |
dc.citation.number | 32 | - |
dc.citation.startPage | 5489 | - |
dc.citation.endPage | 5492 | - |
dc.description.journalRegisteredClass | scie | - |
dc.description.journalRegisteredClass | scopus | - |
dc.identifier.wosid | 000170127200039 | - |
dc.identifier.scopusid | 2-s2.0-0035817350 | - |
dc.relation.journalWebOfScienceCategory | Chemistry, Organic | - |
dc.relation.journalResearchArea | Chemistry | - |
dc.type.docType | Article | - |
dc.subject.keywordPlus | ENANTIOSELECTIVE SYNTHESIS | - |
dc.subject.keywordPlus | OXOCARBOXYLIC ACIDS | - |
dc.subject.keywordAuthor | indium-mediated | - |
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