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dc.contributor.authorLee, SG-
dc.contributor.authorLim, CW-
dc.contributor.authorSong, CE-
dc.contributor.authorKim, IO-
dc.date.accessioned2024-01-21T17:42:48Z-
dc.date.available2024-01-21T17:42:48Z-
dc.date.created2021-09-05-
dc.date.issued1997-12-23-
dc.identifier.issn0957-4166-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/143450-
dc.description.abstractC-2-Symmetric (4S,4'S)-2,2'-bis(o-diphenylphosphinophenyl)-4,4',5,5'- tetrahydro-4,4'-bi(1,3-oxazole) (1, Phos-Bidx) has been designed and synthesized as a chiral ligand for metal-catalyzed reactions. The Phos-Biox 1 was found to be an efficient ligand for rhodium(I)-catalyzed asymmetric reduction of prochiral acetophenones with diphenylsilane to give optically active secondary alcohols of up to 97% ee. (C) 1997 Elsevier Science Ltd. All rights reserved.-
dc.languageEnglish-
dc.publisherPERGAMON-ELSEVIER SCIENCE LTD-
dc.subjectCATALYZED ASYMMETRIC HYDROSILYLATION-
dc.subjectCONTAINING OXAZOLINE LIGANDS-
dc.subjectPHOSPHINE HYBRID LIGAND-
dc.subjectALLYLIC SUBSTITUTION-
dc.subjectCYCLOPROPANATION-
dc.subjectCOMPLEXES-
dc.subjectHYDROGENATION-
dc.subjectOLEFINS-
dc.subjectDERIVATIVES-
dc.subjectALKYLATIONS-
dc.titleA new C-3-symmetric chiral bisphosphine ligand containing a bioxazole backbone: highly enantioselective hydrosilylation of ketones-
dc.typeArticle-
dc.identifier.doi10.1016/S0957-4166(97)00554-5-
dc.description.journalClass1-
dc.identifier.bibliographicCitationTETRAHEDRON-ASYMMETRY, v.8, no.24, pp.4027 - 4031-
dc.citation.titleTETRAHEDRON-ASYMMETRY-
dc.citation.volume8-
dc.citation.number24-
dc.citation.startPage4027-
dc.citation.endPage4031-
dc.description.journalRegisteredClassscie-
dc.description.journalRegisteredClassscopus-
dc.identifier.wosid000071304500010-
dc.identifier.scopusid2-s2.0-0031584574-
dc.relation.journalWebOfScienceCategoryChemistry, Inorganic & Nuclear-
dc.relation.journalWebOfScienceCategoryChemistry, Organic-
dc.relation.journalWebOfScienceCategoryChemistry, Physical-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusCATALYZED ASYMMETRIC HYDROSILYLATION-
dc.subject.keywordPlusCONTAINING OXAZOLINE LIGANDS-
dc.subject.keywordPlusPHOSPHINE HYBRID LIGAND-
dc.subject.keywordPlusALLYLIC SUBSTITUTION-
dc.subject.keywordPlusCYCLOPROPANATION-
dc.subject.keywordPlusCOMPLEXES-
dc.subject.keywordPlusHYDROGENATION-
dc.subject.keywordPlusOLEFINS-
dc.subject.keywordPlusDERIVATIVES-
dc.subject.keywordPlusALKYLATIONS-
dc.subject.keywordAuthorC//2-symmetric bioxazole ligand-
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