SURFACE-ANALYSIS OF LANTHANUM-MODIFIED COBALT CATALYSTS - INVITED LECTURE

Authors
LEDFORD, JSKIM, YMHOUALLA, MPROCTOR, AHERCULES, DM
Issue Date
1992-03
Publisher
ROYAL SOC CHEMISTRY
Citation
ANALYST, v.117, no.3, pp.323 - 327
Abstract
The effect of the addition of La on the structure of 3% m/m Co/Al2O3 catalysts has been studied by the combined use of X-ray photoelectron spectroscopy, Raman spectroscopy, X-ray diffraction and gravimetric analysis. It was shown that La exists as a highly dispersed La-Al2O3 interaction species for alumina carriers impregnated with La and calcined at 600-degrees-C. For 3% m/m Co/Al2O3 catalysts containing La, little effect is observed for La/Al atomic ratios below 0.0075. For higher La loadings, an increase in Co dispersion is observed owing to suppression of Co3O4 formation. Tetrahedral Co2+ and a small amount of an La-Co surface phase are formed. Formation of tetrahedral Co2+ is caused by migration of Co from the La-Co surface phase into the alumina support during calcination at 600-degrees-C.
Keywords
PHOTOELECTRON-SPECTROSCOPY; PHOTOELECTRON-SPECTROSCOPY; CATALYST; SURFACE ANALYSIS; RAMAN SPECTROSCOPY; X-RAY PHOTOELECTRON SPECTROSCOPY; SURFACE PHASE
ISSN
0003-2654
URI
https://pubs.kist.re.kr/handle/201004/146458
DOI
10.1039/an9921700323
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KIST Article > Others
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