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dc.contributor.authorYOO, BR-
dc.contributor.authorJUNG, IN-
dc.contributor.authorLEE, ME-
dc.contributor.authorKIM, CH-
dc.date.accessioned2024-01-21T23:40:11Z-
dc.date.available2024-01-21T23:40:11Z-
dc.date.created2021-09-02-
dc.date.issued1991-10-20-
dc.identifier.issn0253-2964-
dc.identifier.urihttps://pubs.kist.re.kr/handle/201004/146725-
dc.description.abstractThe reaction of dichlorophenylvinylsilane with tert-butyllithium in hydrocarbon solvents at room temperature or below generated the Z and E-isomers of 1-chloro-1-phenyl-2-neopentylsilene. The intermediates were trapped by cyclopentadiene, anthracene and methoxytrimethylsilane to give a consistent 90/10 ratio for the Z-silene to E-silene adduct. This result was interpreted as an evidence for stereochemical induction in the silene generation reaction.-
dc.languageEnglish-
dc.publisherKOREAN CHEMICAL SOC-
dc.subjectSILENE STEREOCHEMISTRY-
dc.subjectALPHA-LITHIOSILANES-
dc.subject"1-METHYL-1-PHENYL-2-NEOPENTYLSILENE-
dc.titleSTEREOCHEMICAL INDUCTION IN THE GENERATION OF 1-CHLORO-1-PHENYL-2-NEOPENTYLSILENE-
dc.typeArticle-
dc.description.journalClass1-
dc.identifier.bibliographicCitationBULLETIN OF THE KOREAN CHEMICAL SOCIETY, v.12, no.5, pp.517 - 520-
dc.citation.titleBULLETIN OF THE KOREAN CHEMICAL SOCIETY-
dc.citation.volume12-
dc.citation.number5-
dc.citation.startPage517-
dc.citation.endPage520-
dc.description.journalRegisteredClassscie-
dc.identifier.wosidA1991GP60400018-
dc.relation.journalWebOfScienceCategoryChemistry, Multidisciplinary-
dc.relation.journalResearchAreaChemistry-
dc.type.docTypeArticle-
dc.subject.keywordPlusSILENE STEREOCHEMISTRY-
dc.subject.keywordPlusALPHA-LITHIOSILANES-
dc.subject.keywordPlus"1-METHYL-1-PHENYL-2-NEOPENTYLSILENE-
dc.subject.keywordAuthorstereochemical-
dc.subject.keywordAuthorinduction-
dc.subject.keywordAuthorgeneration-
dc.subject.keywordAuthor1-chloro-1-phenyl-2-neopentylsilene-
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