SYNTHESIS AND PROPERTIES OF DIAMINEPLATINUM(II) AND DIAMINEPLATINUM(IV) COMPLEXES INVOLVING CYCLOHEXYLIDENEMALONATE LIGAND

Abstract

New diamineplatinum(II) complexes of cyclohexylidenemalonate (chm) ligand, A(2)Pt(OOC)(2)C=C(CH2)(4)CH2 (1, A(2)=ethylenediamine (en); 2, A(2)=propylenediamine (pn); 3, A=NH3; 4, A=isopropylamine (ipa)) have been prepared. Their oxidation with H2O2 has led to the corresponding dihydroxoplatinum(IV) complexes: cis, cis, trans-A(2)Pt((OOC)2C=C (CH2)(4)CH2)(OH)(2) (5, A(2)=en; 6, A(2)=pn; 7, A=NH3; 8, A=ipa). The title complexes have been characterized by means of various spectroscopies and X-ray crystallography. 5 crystallizes in the monoclinic space group P2(1)/a (Z 4) with a=12.098(7) Angstrom, b=9.552(2) Angstrom, c 16.258(4) Angstrom, beta=98.03(5)degrees and V=1860(1) Angstrom.(3) The structure was refined to R=0.074. The local geometry around platinum atom is approximately octahedral with each hydroxide group in trans position. These platinum complexes are stable in aqueous solution. Pt(IV) complexes are readily reduced to the corresponding Pt(II) complexes by ascorbic acid.